CHRONIC TOXICITY OF NIVALENOL, 3, 4, 7, 15-TETRAHYDROXY-12, 13-EPOXY-TRICHOTHEC-9-EN-8-ONE, TO MICE

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photochemical rearrangement of 8- methyl spiro [2.5] oct-7-en-4-one to 4-methyl spiro [2.5] oct-4-en-6-one

irradiation of &methyl; spiro [2.5] oct-7-en-4-one through its singlet excited state resulted in the formation of 4-methyl spiro [2.5] oct-4-en -6-one. we have used the cyclopropyl moiety in the molecule as a probe to study the operating mechanism in the photochemistry of ?, ?-unsaturated compounds. the results showed that this photoisomerization probably occurs through a concerted process.

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ژورنال

عنوان ژورنال: Mycotoxins

سال: 1988

ISSN: 0285-1466,1881-0128

DOI: 10.2520/myco1975.1988.1supplement_105